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A Colorimetric Method for Measuring Iron Content in Plants
Published on: September 7, 2018
Physical properties of iron-sulfur Fe6S6 superclusters important for biological systems
Julita Ozga1, Marek Matusiewicz, Jacek Kasperczyk
1Materials Science Department, Technical University of Czestochowa, 42 200 Czestochowa, Poland.
Abstract:
The theoretical analysis of the thermal and magnetic properties of iron-sulfur superclusters has been studied by taking into account Heisenberg interactions and resonance delocalizations (double exchange interactions). The numerical calculations are based on the determination of the lowest energy states for different values of spins (from S = 0.5 to S = 12.5) and Heisenberg exchange integrals. It is shown that the spin magnetic susceptibility of the iron-sulfur superclusters decreases with increasing temperature and increases with increasing the double exchange parameter. In contrast to the susceptibility, the heat capacity decreases with the increasing values of the double exchange parameter. It was theoretically found that spin of ground state for the iron-sulfur supercluster is equal to 0.5. Based on our results, we can state that the Heisenberg model of spin interactions describes the thermodynamic properties of the iron-sulfur superclusters which are the important constituents of proteins and enzymes.
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