Multiphoton ionization and Coulomb explosion of C2H5Br clusters: a mass spectrometric and charge density study

Using time-of-flight mass spectrometry (TOFMS), laser-induced photochemistry of ethyl bromide clusters has been investigated at three different wavelengths (viz. 266, 355 and 532  nm) utilizing nanosecond laser pulses of ~5 × 10(9)  W/cm(2). An interesting finding of the present work is the observation of multiply charged atomic ions of carbon and bromine at 355 and 532  nm, arising from the Coulomb explosion of (C(2)H(5)Br)(n) clusters. At 266  nm, however, the (C(2)H(5)Br)(n) clusters were found to exhibit the usual multiphoton dissociation/ionization behaviour. The TOFMS studies are complemented by measuring the total charge density of the ionized volume at 266, 355 and 532  nm, using the parallel plate method, and the charge densities were found to be ~2 × 10(9), 6 × 10(9) and 2 × 10(11)  charges/cm(3), respectively. The significantly higher charge density and the presence of energetic, multiply charged atomic ions at 532  nm are explained by the higher ponderomotive energy of the 532  nm photon, coupled with the Coulomb stability of the residual multiply charged ethyl bromide clusters generated upon laser irradiation, due to their larger effective cluster size at 532  nm than at 355 and 266  nm.