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Updated: Jun 2, 2026
Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Butylphenyl-functionalized palladium nanoparticles as effective catalysts for the electrooxidation of formic acid
Zhi-You Zhou1, Xiongwu Kang, Yang Song
1Department of Chemistry and Biochemistry, University of California, 1156 High Street, Santa Cruz, California 95064, USA.
Abstract:
Monodisperse butylphenyl-functionalized palladium (Pd-BP, dia. 2.24 nm) nanoparticles were synthesized through co-reduction of butylphenyldiazonium and H(2)PdCl(4) by NaBH(4). Because of this unique surface functionalization and a high specific electrochemical surface area (122 m(2) g(-1)), the Pd-BP nanoparticles exhibited a mass activity ∼4.5 times that of commercial Pd black for HCOOH electrooxidation.
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