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Dichlorido{2-(morpholin-4-yl)-N-[1-(pyridin-2-yl)ethyl-idene]ethanamine-κN,N',N''}copper(II) monohydrate
Nura Suleiman Gwaram1, Hamid Khaledi, Hapipah Mohd Ali
1Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
Abstract:
In the title compound, [CuCl(2)(C(13)H(19)N(3)O)]·H(2)O, the tridentate Schiff base ligand and the two Cl atoms complete a distorted square-pyramidal coordination geometry around the Cu(II) ion in which the three N atoms and one Cl atom are located in the basal plane and the other Cl atom is at the apical position. In the crystal, O-H⋯Cl hydrogen bonds link the complex mol-ecules and the uncoordinated water mol-ecules into infinite chains along the a axis. The chains are further connected into a three-dimensional network via C-H⋯O and C-H⋯Cl inter-actions.
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