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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Dibromido{2-(morpholin-4-yl)-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}cadmium
Nura Suleiman Gwaram1, Hamid Khaledi, Hapipah Mohd Ali
1Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
Abstract:
The Cd(II) ion in the title compound, [CdBr(2)(C(13)H(19)N(3)O)], is five-coordinated by the N,N',N''-tridentate Schiff base ligand and two Br atoms in a distorted square-pyramidal geometry. In the crystal, inter-molecular C-H⋯O and C-H⋯Br hydrogen bonds link adjacent mol-ecules into layers parallel to the ab plane. An intra-molecular C-H⋯Br inter-action is also observed.
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