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A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
Published on: August 16, 2018
{2-[(Dimethyl-amino)-meth-yl]phen-yl}bis-(4-methyl-phen-yl)bis-muthane
Acta Crystallographica. Section E, Structure Reports Online
|April 28, 2011
Abstract:
The title compound, [Bi(C(7)H(7))(2)(C(9)H(12)N)], was obtained by treating chlorodi(p-tol-yl)bis-muthane with o-lithio-N,N-dimethyl-benzyl-amine. An intra-molecular Bi⋯N nonbonding inter-action is observed in the distorted trigonal triaryl-bis-muth coordination of the title compound.
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