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Updated: Jun 2, 2026
![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
catena-Poly[[[2-(pyridin-2-yldisulfan-yl)pyridine-κN,S]copper(I)]-μ(1,5)-dicyanamido]
Shixi Wu1, Wei Jiang, Fengsheng Li
1National Special Superfine Powder Engineering Research Center, Nanjing University of Science and Technology, Nanjing 210094, People's Republic of China.
Abstract:
In the title compound, [Cu(C(2)N(3))(C(10)H(8)N(2)S(2))](n), the Cu(I) atoms are connected by bridging dicyanamide ligands, forming chains parallel to [100]. Each Cu(I) atom displays a tetra-hedral coordination environment, formed by one S atom and three N atoms from one 2-(pyridin-2-yldisulfan-yl)pyridine and two dicyanamide ligands. The crystal structure is stabilized by C-H⋯N hydrogen bonds, forming a three-dimensional network.
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