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Updated: Jun 2, 2026
Atomically Defined Templates for Epitaxial Growth of Complex Oxide Thin Films
Published on: December 4, 2014
Solid state precursor strategy for synthesizing hollow TiO2 boxes with a high percentage of reactive {001} facets
Shuifen Xie1, Xiguang Han, Qin Kuang
1State Key Laboratory for Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, PR China.
Abstract:
Three-dimensional, hollow, anatase TiO(2) boxes, each was enclosed by six single-crystalline TiO(2) plates exposed with highly reactive {001} facets, were facilely obtained by calcining a cubic TiOF(2) solid precursor at 500-600 °C. The formation of such particular nanostructures is attributed to the hard self-template restriction and the adsorption of F(-) ions from the TiOF(2).
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