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Updated: Jun 2, 2026

Preparation and Friction Force Microscopy Measurements of Immiscible, Opposing Polymer Brushes
Published on: December 24, 2014
Direct Synthesis of Poly(potassium 3-sulfopropyl methacrylate) Cylindrical Polymer Brushes via ATRP Using a
Youyong Xu1, Andreas Walther, Axel H E Müller
1Makromolekulare Chemie II and Bayreuther Zentrum für Kolloide und Grenzflächen, Universität Bayreuth, D-95440 Bayreuth, Germany.
Abstract:
A supramolecular complex between an ionic monomer 3-sulfopropyl methacrylate (SPMAK) and crown ether 18-crown-6 (18C6) has been employed to prepare a strong anionic cylindrical polyelectrolyte brush poly(potassium 3-sulfopropyl methacrylate) (PSPMAK) by atom transfer radical polymerization (ATRP) in polar solvent dimethyl sulfoxide (DMSO). This strategy solved the problem of the solubilities of the incompatible hydrophobic poly-initiator and hydrophilic ionic monomer. The formation of the PSPMAK brush is well proven by (1) H NMR, aqueous gel permeation chromatography (GPC), dynamic light scattering (DLS), static light scattering (SLS), atomic force microscopy (AFM), and cryogenic transmission electron microscopy (cryo-TEM) measurements. Cleavage of the side chains and further analysis reveal that the initiating efficiency of the polymerization is as low as 0.35.
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