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Updated: Apr 29, 2026
08:25
Chemical Vapor Deposition of an Organic Magnet, Vanadium Tetracyanoethylene
Published on: July 3, 2015
11.3K
(Methoxo-κO)oxidobis(quinolin-8-olato-κN,O)vanadium(V)
Summary
This study details the crystal structure of a vanadium(V) complex, [V(C(9)H(6)NO)(2)(CH(3)O)O]. The complex features a distorted octahedral geometry around the central vanadium atom, stabilized by quinolin-8-olate ligands.
Area of Science:
- Inorganic Chemistry
- Crystallography
- Coordination Chemistry
Background:
- Vanadium complexes are of interest due to their diverse oxidation states and coordination geometries.
- Quinolin-8-olate is a versatile chelating ligand used in coordination chemistry.
Purpose of the Study:
- To characterize the crystal structure of the novel vanadium(V) complex, [V(C(9)H(6)NO)(2)(CH(3)O)O].
- To investigate the coordination environment and intermolecular interactions within the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of bond lengths, angles, and intermolecular interactions (hydrogen bonds, π-π stacking) was performed.
Main Results:
- The central vanadium(V) atom exhibits a distorted octahedral coordination environment.
- The complex is formed by two bis-chelating quinolin-8-olate ligands, one oxido ligand, and one methoxo ligand.
- Weak intermolecular C-H⋯O hydrogen bonds and C-H⋯π interactions link molecules into chains along the b axis.
Conclusions:
- The study provides a detailed structural description of a new vanadium(V) complex.
- The observed intermolecular interactions offer insights into crystal packing and supramolecular assembly.
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