Related Experiment Video
Updated: Jun 1, 2026

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
Published on: January 19, 2016
4-Nitro-phenyl 2-methyl-benzoate
Abstract:
The title compound, C(14)H(11)NO(4), crystallizes with two mol-ecules in the asymmetric unit. The major conformational difference between these two mol-ecules is the dihedral angle between the aromatic rings, namely 36.99 (5) and 55.04 (5)°. The nitro groups are coplanar with the phenyl rings to which they are attached, the O-N-C-C torsion angles being -1.9 (3) and 1.0 (3)° in the two mol-ecules.
Related Concept Videos
Electrophilic Aromatic Substitution: Nitration of Benzene
NMR Spectroscopy of Benzene Derivatives
Reactions at the Benzylic Position: Oxidation and Reduction
meta-Directing Deactivators: –NO2, –CN, –CHO, –⁠CO2R, –COR, –CO2H
Acidity and Basicity of Alcohols and Phenols
Nucleophilic Aromatic Substitution: Elimination–Addition

