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Summary

This summary is machine-generated.

This study details the crystal structure of a C(14)H(11)NO(4) compound, revealing distinct molecular conformations. Key differences were observed in the dihedral angles between aromatic rings and the coplanarity of nitro groups.

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Area of Science:

Crystallography
Molecular structure determination
Organic chemistry

Background:

Understanding molecular conformation is crucial in chemistry.
C(14)H(11)NO(4) is a compound with potential applications in various chemical fields.
Crystallization is a primary method for determining precise molecular geometries.

Purpose of the Study:

To elucidate the crystal structure of the title compound, C(14)H(11)NO(4).
To analyze the conformational differences between molecules within the asymmetric unit.
To investigate the spatial arrangement of functional groups, specifically nitro groups and aromatic rings.

Main Methods:

Single-crystal X-ray diffraction was employed to determine the crystal structure.
Analysis of the asymmetric unit revealed the presence of two distinct molecules.
Geometric parameters, including dihedral and torsion angles, were precisely measured.

Main Results:

The title compound, C(14)H(11)NO(4), crystallizes with two molecules in the asymmetric unit.
A significant conformational difference was observed in the dihedral angle between the aromatic rings (36.99(5)° and 55.04(5)°).
Nitro groups were found to be coplanar with their attached phenyl rings, with specific O-N-C-C torsion angles of -1.9(3)° and 1.0(3)°.

Conclusions:

The crystal structure analysis provides precise geometric data for C(14)H(11)NO(4).
The observed conformational variations highlight the flexibility of the molecule in the solid state.
The coplanarity of nitro groups suggests specific electronic interactions within the molecule.