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Updated: Jun 1, 2026
07:28
Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization
Published on: November 27, 2015
2,2'-[Ethyl-enebis(azanediyl-methyl-ene)]diphenol
Summary
This study details the crystal structure of a novel organic compound, revealing a unique zigzag molecular chain. Intermolecular hydrogen bonding between imino and hydroxyl groups results in an organized layered structure.
Area of Science:
- Organic Chemistry
- Crystallography
- Supramolecular Chemistry
Background:
- Understanding the relationship between molecular structure and macroscopic properties is crucial in materials science.
- Hydrogen bonding plays a significant role in dictating crystal packing and material characteristics.
Purpose of the Study:
- To elucidate the crystal structure and intermolecular interactions of the title compound, C(16)H(20)N(2)O(4).
- To investigate the role of hydrogen bonding in the formation of the observed layered structure.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of hydrogen bonding networks and molecular geometry was performed.
Main Results:
- The molecule possesses a zigzag chain connecting two hydroxy-phenyl rings and lies about a center of inversion.
- The imino group acts as a hydrogen bond donor to the hydroxyl group of an adjacent molecule.
- This intermolecular hydrogen bonding leads to the formation of a distinct layer structure.
Conclusions:
- The crystal structure of C(16)H(20)N(2)O(4) is characterized by specific zigzag chain conformation and intermolecular hydrogen bonding.
- The identified hydrogen bonding motif is responsible for the assembly into a layered supramolecular architecture.
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