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Updated: Jun 1, 2026
11:51
Facile Preparation of 4-Substituted Quinazoline Derivatives
Published on: February 15, 2016
3-Acetyl-6-chloro-2-methyl-4-phenyl-quinolinium perchlorate
Abstract:
In the title mol-ecular salt, C(18)H(15)ClNO(+)·ClO(4) (-), the quinolin-ium ring system is approximately planar, with a maximum deviation of 0.027 (1) Å. The dihedral angle formed between the mean planes of the quinolinium ring system and the benzene ring is 78.46 (3)°. In the crystal structure, inter-molecular N-H⋯O and C-H⋯O hydrogen bonds link the cations and anions into a three-dimensional network. The crystal structure is further consolidated by C-H⋯π inter-actions.
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o-hydroxy phenols are oxidized to o-quinones and p-hydroxy phenols to p-quinones. Such redox reactions involve the transfer of two electrons and two protons. The reversible redox property is crucial in...
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