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Updated: Jun 1, 2026
10:44
Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
Published on: April 19, 2019
4,4'-(1,1,1,3,3,3-Hexafluoro-propane-2,2-diyl)dibenzoic acid
Summary
The crystal structure of a novel organic compound reveals twisted benzene rings and a unique wave-like layered arrangement. This supramolecular architecture is formed through specific hydrogen bonding interactions between molecules.
Area of Science:
- Crystallography
- Supramolecular Chemistry
- Organic Chemistry
Background:
- Understanding the three-dimensional arrangement of molecules in crystals is crucial for predicting material properties.
- Hydrogen bonding plays a significant role in the self-assembly of organic compounds into ordered structures.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(17)H(10)F(6)O(4).
- To investigate the intermolecular interactions and supramolecular assembly in the solid state.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of hydrogen bonding networks (O-H⋯O and C-H⋯F) and dihedral angles between aromatic rings.
Main Results:
- The crystal structure of C(17)H(10)F(6)O(4) was determined, revealing a significant dihedral angle of 67.43° between the two benzene rings.
- Adjacent molecules form a wave-like layered supramolecular structure mediated by O-H⋯O and C-H⋯F hydrogen bonds.
Conclusions:
- The study provides detailed structural insights into the packing of C(17)H(10)F(6)O(4) in the solid state.
- The observed supramolecular arrangement highlights the importance of specific hydrogen bonding in dictating crystal architecture.
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