N,N'-Bis(phenyl-sulfon-yl)maleamide
Summary
The crystal structure of C(16)H(14)N(2)O(6)S(2) reveals inversion symmetry, with molecules forming intramolecular and intermolecular hydrogen bonds. This finding provides insights into the compound
Area of Science:
- Crystallography and Molecular Structure
- Organic Chemistry
- Supramolecular Chemistry
Background:
- Understanding the three-dimensional arrangement of atoms in organic molecules is crucial for predicting their properties and reactivity.
- Hydrogen bonding plays a significant role in molecular recognition, self-assembly, and the stabilization of crystal structures.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(16)H(14)N(2)O(6)S(2).
- To investigate the presence and nature of symmetry elements within the molecule.
- To identify and characterize hydrogen bonding interactions, both intramolecular and intermolecular.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of the crystallographic data to identify symmetry operations and atomic coordinates.
- Geometric analysis to confirm the presence and geometry of hydrogen bonds.
Main Results:
- The title compound, C(16)H(14)N(2)O(6)S(2), crystallizes with molecules exhibiting crystallographic inversion symmetry.
- The asymmetric unit contains one half-molecule, indicating a crystallographic center of symmetry.
- Both intramolecular and intermolecular N-H⋯O hydrogen bonds were identified, contributing to the overall crystal packing.
Conclusions:
- The crystal structure determination provides a detailed understanding of the molecular architecture of C(16)H(14)N(2)O(6)S(2).
- The observed inversion symmetry and hydrogen bonding patterns offer insights into the compound's solid-state behavior and potential intermolecular interactions.
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