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Updated: Aug 15, 2026

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Crystal structure and Hirshfeld surface analysis of
Nikhila Pai1, Sabine Foro2, B Thimme Gowda1,3
1Department of Chemistry, Mangalore University, Mangalagangotri 574 199, Mangalore, India.
Abstract:
The asymmetric unit of the title thia-zole derivative containing a sulfonyl-hydrazinic moiety, C9H8ClN3O3S2·H2O, consists of two independent mol-ecules and two water mol-ecules. The central parts of the mol-ecules are twisted as both the mol-ecules are bent at both the S and N atoms. In the crystal, N-H⋯N, N-H⋯O, C-H⋯O and O-H⋯O hydrogen-bonding inter-actions connect the mol-ecules, forming layers parallel to the ab plane. Two-dimensional fingerprint plots associated with the Hirshfeld surface show that the largest contributions to the crystal packing come from O⋯H/H⋯O (32.9%) and H⋯H (22.6%) inter-actions.
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