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Updated: Jun 1, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
Published on: August 16, 2018
{2-Hydr-oxy-6-[(2-oxidophen-yl)imino-methyl-κN,O]phenolato-κO}phenyl-boron
Araceli Vega1, Hugo Tlahuext, Herbert Höpfl
1Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, Col. Chamilpa, CP 62209, Cuernavaca Mor., Mexico.
Abstract:
The [4.3.0]heterobicyclic title structure, C(19)H(14)BNO(3), is composed of a five-membered OBNC(2) ring and a six-membered OBNC(3) ring, each of which has an approximate envelope conformation. The coordination geometry of the B atom is distorted tetra-hedral. In the crystal structure, centrosymmetrically related mol-ecules are associated through pairs of O-H⋯O hydrogen bonds.
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