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Updated: Jun 1, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
N-Benzoyl-4-chloro-benzene-sulfonamide
Abstract:
The asymmetric unit of the title compound, C(13)H(10)ClNO(3)S, contains two independent mol-ecules. The mol-ecules have C-S-N-C torsion angles of -70.0 (2) and 61.3 (2)° for mol-ecules 1 and 2, respectively. The dihedral angles between the sulfonyl benzene rings and the -SO(2)-NH-C-O segments are 72.0 (1) and 77.3 (1)° for mol-ecules 1 and 2, respectively, and the dihedral angles between the sulfonyl and the benzoyl benzene rings are 62.8 (1) and 78.6 (1)°, respectively. In the crystal, mol-ecules 1 and 2 are linked by pairs of N-H⋯O hydrogen bonds, forming inversion dimers.
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