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Summary

This study details the crystal structure of a zwitterionic compound, C(17)H(17)NO(3). The molecule features iminium and enolate groups in a trans configuration, with specific dihedral angles and hydrogen bonding interactions observed in its crystalline form.

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Area of Science:

Crystallography
Organic Chemistry
Molecular Structure

Background:

Zwitterionic compounds exhibit unique chemical properties due to their internal charge separation.
Understanding molecular conformation and intermolecular interactions is crucial for predicting material properties.

Purpose of the Study:

To elucidate the crystal structure of the title compound, C(17)H(17)NO(3).
To characterize the zwitterionic nature, molecular geometry, and intermolecular interactions in the solid state.

Main Methods:

Single-crystal X-ray diffraction analysis was employed.
Detailed analysis of bond lengths, bond angles, dihedral angles, and hydrogen bonding networks.

Main Results:

The compound crystallizes as a zwitterion with distinct iminium and enolate functionalities.
A trans configuration around the C=N bond and specific dihedral angles between aromatic rings and substituents were determined.
Intramolecular N-H⋯O hydrogen bonding formed an S(6) ring, and intermolecular O-H⋯O bonds created zigzag chains.

Conclusions:

The crystal structure reveals a well-defined molecular architecture with significant intra- and intermolecular interactions.
The observed hydrogen bonding and π-interactions influence the packing and stability of the zwitterionic compound in the solid state.