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![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Poly[μ-4,4'-bipyridine-κN:N'-μ-thio-cyanato-κN:S-copper(I)]
Mario Wriedt1, Sina Sellmer, Christian Näther
1Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, D-24118 Kiel, Germany.
Abstract:
In the crystal structure of the title compound, [Cu(NCS)(C(10)H(8)N(2))](n), the Cu(I) atom is coordinated by two N atoms from two symmetry-related 4,4'-bipyridine (bipy) ligands and one N and one S atom from two symmetry-related thio-cyanate ligands in a distorted tetra-hedral environment. The thio-cyanate ligands bridge the Cu(I) atoms into a zigzag [CuSCN](n) chain running parallel to the a axis. These chains are further connected through two bipy ligands that bridge the Cu(I) centers to generate a two-dimensional brick-like network. The pyridyl planes of the ligands exhibit a dihedral angle of 37.35 (12)°.
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