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NdO(NO(3)).

Ya-Feng Li¹, Li Jin, Dan-Ping Li

¹School of Chemical Engineering, Changchun University of Technology, Changchun 130012, People's Republic of China.

Acta Crystallographica. Section E, Structure Reports Online

|May 18, 2011

Summary

This summary is machine-generated.

Neodymium(III) oxide nitrate, a novel compound, was synthesized using a solvothermal method. Its crystal structure features a ten-coordinated neodymium ion forming a 3D framework of NdO(10) polyhedra.

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Area of Science:

Inorganic Chemistry
Crystallography
Materials Science

Background:

Neodymium(III) oxide nitrate is a novel inorganic compound.
Lanthanum oxide nitrate (LaO(NO3)) serves as a structural reference.

Purpose of the Study:

To synthesize and characterize neodymium(III) oxide nitrate.
To elucidate the crystal structure and coordination environment of the neodymium ion.

Main Methods:

Solvothermal synthesis.
Single-crystal X-ray diffraction analysis.

Main Results:

The title compound, neodymium(III) oxide nitrate, was successfully synthesized via solvothermal reaction.
The neodymium ion (Nd) exhibits ten-coordination, bonded to eight oxygen atoms from nitrate groups and two μ(2)-oxide ions.
A three-dimensional crystal structure is formed through the interconnected NdO(10) polyhedra.

Conclusions:

Neodymium(III) oxide nitrate is isostructural with LaO(NO3).
The study provides detailed insights into the coordination chemistry and structural architecture of this neodymium compound.