![Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F51444.jpg&w=3840&q=50)
[O-Ethyl N-(4-nitro-phen-yl)thio-carbam-ato-κS](tri-p-tolyl-phosphine-κP)gold(I)
Grant A Broker1, Edward R T Tiekink
1Department of Chemistry, The University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, USA.
Abstract:
A nearly linear coordination geometry for Au is found in the title compound, [Au(C(9)H(9)N(2)O(3)S)(C(21)H(21)P)]. The thio-carbamate ligand is orientated so that the aryl group is in close proximity to the Au atom, consistent with an Au⋯π contact [Au⋯Cg = 3.351 (5) Å; Cg is the centroid of the aromatic ring].
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