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Updated: Jun 1, 2026
![Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F60786.jpg&w=3840&q=50)
Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
(E)-4-[(4-Nitro-phen-yl)diazen-yl]phenyl anthracene-9-carboxyl-ate
Abstract:
In the title compound, C(27)H(17)N(3)O(4), the azo group displays a trans conformation and the dihedral angles between the central benzene ring and the pendant anthracene and nitro-benzene rings are 82.94 (7) and 7.30 (9)°, respectively. In the crystal structure, weak C-H⋯O hydrogen bonds, likely associated with a dipole moment present on the mol-ecule, help to consolidate the packing.
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