Related Experiment Video
Updated: Jun 1, 2026

06:35
Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Tetra-ethyl-ammonium l-tartarate dihydrate
Summary
The crystal structure of a compound reveals ions and water molecules forming a two-dimensional network. This network is stabilized by hydrogen bonds, specifically O-H⋯O and C-H⋯O interactions.
Area of Science:
- Crystallography
- Supramolecular Chemistry
- Materials Science
Background:
- Hydrogen bonding plays a crucial role in the self-assembly of molecular structures.
- Understanding crystal packing is essential for predicting material properties.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(8)H(20)N(+)·C(4)H(5)O(6) (-)·2H(2)O.
- To investigate the intermolecular interactions governing the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the atomic arrangement.
- Analysis of hydrogen bonding networks (O-H⋯O and C-H⋯O) was performed.
Main Results:
- The crystal structure consists of organic ions and water molecules.
- A two-dimensional network parallel to the (001) plane was identified.
- The network is formed through a combination of O-H⋯O and C-H⋯O hydrogen bonds.
Conclusions:
- The hydrogen bonding interactions dictate the formation of a stable 2D network in the crystal structure.
- This structural motif provides insights into the supramolecular assembly of similar organic salts and hydrates.
Related Concept Videos
EDTA: Auxiliary Complexing Reagents
EDTA titrations are usually carried out in highly basic conditions, where the fully deprotonated form of EDTA, Y4−, actively complexes with the free metal ions in the solution. Several metal ions precipitate as hydrous oxide (hydroxides, oxides, or oxyhydroxides) under these conditions, lowering the concentration of free metal ions in the solution. For this reason, auxiliary complexing agents or ligands such as ammonia, tartrate, citrate, or triethanolamine are used in EDTA titrations to...
EDTA: Chemistry and Properties
Polydentate ligands are most widely used in complexometric titrations because they form more stable complexes with the metal ions than mono- or bidentate ligands due to the chelate effect. Examples of polydentate ligands are ethylenediaminetetraacetic acid (EDTA), crown ethers, and cryptands. The most important feature of optimal polydentate ligands is the ability to form 1:1 complexes in a single-step process. Amino carboxylic acid derivatives are frequently used as complexing agents. EDTA is...

