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Updated: Jun 1, 2026

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

Tetra-quabis(5-fluoro-saccharinato)nickel(II)

Larnelle Peterson, Jennifer Kelley, Leroy Peterson

    Acta Crystallographica. Section E, Structure Reports Online
    |May 18, 2011
    PubMed

    Abstract:

    In the centrosymmetric title complex, [Ni(C(7)H(3)FNO(3)S)(2)(H(2)O)(4)], the Ni(II) atom exhibits a slightly distorted trans-NiN(2)O(4) octa-hedral coordination. The nitro-gen donors are provided by two 5-fluoro-saccharinate ligands and the oxygen donors are provided by four water mol-ecules. The crystal structure features O-H⋯O and bifurcated O-H⋯(F,O) hydrogen bonds, the latter involving the F atom of the 5-fluoro-saccharinate ligand.

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    Qualitative Analysis03:46

    Qualitative Analysis

    For solutions containing mixtures of different cations, the identity of each cation can be determined by qualitative analysis. This technique involves a series of selective precipitations with different chemical reagents, each reaction producing a characteristic precipitate for a specific group of cations. Metal ions within a group are further separated by varying the pH, heating the mixture to redissolve a precipitate, or adding other reagents to form complex ions.
    For instance, group IV...

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