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Updated: Jun 1, 2026

Discovery and Synthesis Optimization of Isoreticular Al(III) Phosphonate-Based Metal-Organic Framework Compounds Using High-Throughput Methods
Published on: October 6, 2023
{μ-[2-(Dimethyl-amino)phen-yl](2-fluoro-phen-yl)methano-lato}penta-methyl-dialuminum(III)
Abstract:
Each of the Al atoms in the title compound, [Al(2)(CH(3))(5)(C(15)H(15)FNO)], is four-coordinated in a distorted tetra-hedral geometry. The dimethyl-aluminium centre is bound by the N and the O atoms of the (2-dimethyl-amino-phen-yl)(2-fluoro-phen-yl)methano-late ligand. The second Al atom is bound by the methano-late O atom and by three methyl C atoms. The crystal studied was a racemic twin with a 0.4 (2):0.6 (2) domain ratio.
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