Related Experiment Video

Updated: Jun 1, 2026

Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine
11:04

Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine

Published on: June 13, 2022

1-(3-Ammonio-methyl-2,4,6-trimethyl-benz-yl)-3-(2,4,6-trimethyl-phen-yl)imidazol-1-ium dibromide monohydrate

Chao Zhang, Yong Ren, Mei-Ming Luo

    Acta Crystallographica. Section E, Structure Reports Online
    |May 18, 2011
    PubMed

    Abstract:

    In the title compound, C(25)H(35)N(3) (2+)·2Br(-)·H(2)O, the dihedral angles between the imidazole ring and the two outer benzene rings are 80.16 (16) and 69.40 (18)°. The component species are linked by N-H⋯Br, O-H⋯Br and C-H⋯Br hydrogen bonds.

    More Related Videos

    Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
    11:45

    Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles

    Published on: August 22, 2018

    Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions
    04:38

    Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions

    Published on: July 28, 2022

    Related Experiment Videos

    Last Updated: Jun 1, 2026

    Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine
    11:04

    Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine

    Published on: June 13, 2022

    Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
    11:45

    Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles

    Published on: August 22, 2018

    Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions
    04:38

    Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions

    Published on: July 28, 2022

    Related Concept Videos

    Diazonium Group Substitution: –OH and –H01:19

    Diazonium Group Substitution: –OH and –H

    Nitrous acid, a weak acid, is prepared in situ via the reaction of sodium nitrite with a strong acid under cold conditions. This nitrous acid prepared in situ reacts with primary arylamines to form arenediazonium salts. Such reactions are known as diazotization reactions. As shown in Figure 1, the formation of arenediazonium salts begins with the decomposition of nitrous acid in an acidic solution to give nitrosonium ions.
    Alkyl Halides02:45

    Alkyl Halides

    Structural Properties
    Alkyl halides are halogen-substituted alkanes wherein one or more hydrogen atoms of an alkane is replaced by a halogen atom such as fluorine, chlorine, bromine, or iodine. The carbon atom in an alkyl halide is bonded to the halogen atom, which is sp3-hybridized and exhibits a tetrahedral shape.
    Unlike alkyl halides, compounds in which a halogen atom is bonded to an sp2 -hybridized carbon atom of a carbon-carbon double bond (C=C) are called vinyl halides. Whereas aryl...
    Basicity of Heterocyclic Aromatic Amines01:25

    Basicity of Heterocyclic Aromatic Amines

    Heterocyclic amines, where the N atom is a part of an alicyclic system, are similar in basicity to alkylamines. Interestingly, the heterocyclic amine having a nitrogen atom as part of an aromatic ring has much less basicity than its corresponding alicyclic counterpart. For this reason, as presented in Figure 1, piperidine (pKb = 2.8) is significantly more basic than pyridine (pKb = 8.8).

    Articles linked to this work by shared authors, journal, and citation graph.

    Vibrational and structural properties of tetramethyltin under pressure.

    The Journal of chemical physics·2013

    Adcyap1r1 genotype, posttraumatic stress disorder, and depression among women exposed to childhood maltreatment.

    Depression and anxiety·2013

    Surgical treatment of ossification of the ligamentum flavum associated with dural ossification in the thoracic spine.

    Journal of clinical neuroscience : official journal of the Neurosurgical Society of Australasia·2012

    Molecular characterization of heterogeneous mesenchymal stem cells with single-cell transcriptomes.

    Biotechnology advances·2012

    Current status and challenge of Human Parasitology teaching in China.

    Pathogens and global health·2012

    Class IIa bacteriocins: diversity and new developments.

    International journal of molecular sciences·2012

    Crystal structure of 1-(piperidin-1-yl)butane-1,3-dione.

    Acta crystallographica. Section E, Structure reports online·2015

    Crystal structure of methyl 1-methyl-3,5-diphenyl-7-tosyl-3,6,7,11b-tetra-hydro-pyrazolo-[4',3':5,6]pyrano[3,4-c]quinoline-5a(5H)-carboxyl-ate.

    Acta crystallographica. Section E, Structure reports online·2015

    Crystal structure of 4-amino-1-(4-methyl-benz-yl)pyridinium bromide.

    Acta crystallographica. Section E, Structure reports online·2015

    Crystal structure of (Z)-3-benz-yloxy-6-[(2-hy-droxy-anilino)methyl-idene]cyclo-hexa-2,4-dien-1-one.

    Acta crystallographica. Section E, Structure reports online·2015

    Crystal structure of bis-(1-benzyl-1H-1,2,4-triazole) perchloric acid monosolvate.

    Acta crystallographica. Section E, Structure reports online·2015

    Crystal structure of 2-(di-phenyl-phos-phanyl)phenyl 4-(hy-droxy-meth-yl)benzoate.

    Acta crystallographica. Section E, Structure reports online·2015

    Aerobic base-catalyzed rearrangement in triterpenic indoles: an access to spirooxindoles, indolenines, and quinolones.

    Organic & biomolecular chemistry·2026

    Isolated Oral and Esophageal Mucosal Injury as a Rare Oxcarbazepine Adverse Drug Reaction: A Case Report.

    Cureus·2026

    Zinc-Catalyzed Dehydrogenative Alkynylation of BN-Polycyclic Aromatics.

    Angewandte Chemie (International ed. in English)·2026

    Electrochemically Induced Three-Component Synthesis of Substituted 5-Aminotetrazoles from Isocyanides, Amines, and Azides.

    The Journal of organic chemistry·2026

    Bi(OTf)3-Catalyzed Diastereoselective Three-Component Povarov Reaction of Aminoquinones toward Tetrahydroquinolinequinones.

    The Journal of organic chemistry·2026

    Enantioselective Synthesis of Halogenated Adamantane-Based Amino Acid Derivatives via Rhodium-Catalyzed C-H Bond Amination.

    The Journal of organic chemistry·2026
    See all related articles
    JoVE
    x logofacebook logolinkedin logoyoutube logo
    ABOUT JoVE
    OverviewLeadershipBlogJoVE Help Center
    AUTHORS
    Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
    LIBRARIANS
    TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
    RESEARCH
    JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
    EDUCATION
    JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
    Terms & Conditions of Use
    Privacy Policy
    Policies
    Jove
    Visualize
    Contact Us