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Updated: Jun 1, 2026

Design, Synthesis, and Photochemical Properties of Clickable Caged Compounds
Published on: October 15, 2019
catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato]
Abstract:
In the title coordination polymer, [Cu(C(2)O(4))(C(12)H(8)N(2))](n), the Cu(II) atom is six-coordinated by four O atoms from two oxalate ligands and two N atoms from one 1,10-phenanthroline (phen) ligand in a distorted octa-hedral coordination geometry. The oxalate anions act as bis-bidentate ligands, bridging the Cu-phen units in zigzag chains extending parallel to [100]. Inter-chain C-H⋯O hydrogen bonding and π-π stacking inter-actions [centroid-centroid distance = 3.7439 (17) Å] assemble neighboring chains, forming a three-dimensional supra-molecular network.
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