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Updated: Jun 1, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
Published on: August 16, 2018
3-(3-Cyano-phen-yl)-N-phenyl-oxirane-2-carboxamide
1College of Chemistry and Chemical Engineering, China West Normal University, Nanchong 637002, People's Republic of China.
Abstract:
In the title compound, C(16)H(12)N(2)O(2), both terminal benzene rings are located at the same side of the central epoxide ring, showing a cis conformation. The epoxide ring makes dihedral angles of 76.59 (10) and 62.40 (11)° with the phenyl and cyano-phenyl rings, respectively. Inter-molecular N-H⋯O and weak C-H⋯O hydrogen bonding is present in the crystal structure.
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