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Updated: Jun 1, 2026

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
Published on: August 22, 2018
1,3,5,7-Tetra-kis(4-iodo-phen-yl)adamantane benzene tetra-solvate
Abstract:
The title mol-ecule, C(34)H(28)I(4)·4C(6)H(6), has crystallographic symmetry and crystallizes with four symmetry-related benzene solvent mol-ecules. The phenyl group is eclipsed with one of the adamantane C-C bonds. The tetra-phenyl-adamantane units and the benzene solvent mol-ecules are connected by weak inter-molecular phen-yl-benzene C-H⋯π and benzene-benzene C-H⋯π inter-actions. In the crystal, mol-ecules are linked along the c-axis direction via the iodo-phenyl groups by a combination of weak inter-molecular I⋯I [3.944 (1) Å] and I⋯π(phen-yl) [3.608 (6) and 3.692 (5) Å] inter-actions.
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