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Updated: Jun 1, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
3-[(2-Hy-droxy-1-naphth-yl)(pyrrolidin-1-yl)meth-yl]benzonitrile
1Biochemical and Environmental Engineering College, Nanjing Xiaozhuang University, Nanjing 210017, People's Republic of China.
Abstract:
The title compound, C(22)H(20)N(2)O, was obtained from the condensation reaction of 3-formyl-benzonitrile, 2-naphthol and pyrrolidine. There are two mol-ecules in the asymmetric unit, having similar conformations. Intra-molecular O-H⋯N and C-H⋯O hydrogen bonds occur, with only van der Waals forces between mol-ecules. The dihedral angles between the naphthalene ring system and the phenyl ring in the two molecules are 75.28 (10) and 76.07 (11)°. The five-membered rings adopt half-chair conformations.
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