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Updated: Jun 1, 2026
![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
[2-Hydroxy-N'-(4-oxo-4-phenyl-butan-2-yl-idene)benzohydrazidato(2-)]pyridine-copper(II)
Shu-Ping Zhang1, Ying Wei, Si-Chang Shao
1Department of Chemistry, Fuyang Normal College, Fuyang, Anhui 236041, People's Republic of China.
Abstract:
The mononuclear title complex, [Cu(C(17)H(14)N(2)O(3))(C(5)H(5)N)], was synthesized by the reaction of CuCl(2)·2H(2)O with N-(4-oxo-4-phenyl-butan-2-yl-idene)benzohydrazide (H(2)L). The central Cu(II) atom exhibits a distorted square-planar coordination geometry, defined by two O atoms, one N atom from the ligand and one pyridine N atom with Cu-N distances of 1.874 (4) and 1.963 (4) Å, while the Cu-O distances are 1.857 (3) and 1.890 (3) Å. An intra-molecular O-H⋯N inter-action occurs.
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