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Updated: Jun 1, 2026
Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
A highly symmetric diamond-like assembly of cyclotricatechylene-based tetrahedral cages
Brendan F Abrahams1, Berin A Boughton, Nicholas J FitzGerald
1School of Chemistry, University of Melbourne, Victoria 3010, Australia. bfa@unimelb.edu.au
Abstract:
The combination of six Cu(II) centres with four cyclotricatechylene (ctc(6-)) ligands generates large (Cu(6)ctc(4))(12-) cages with the topology of the tetrahedron. The anionic tetrahedral cages are cemented together, triangular face to triangular face, by Na(+) cations together with water molecules to generate a highly symmetric diamond-like assembly (space group Fd-3m, the same as that of diamond itself) whose adamantane-like units have an iodide ion at the centre of every cyclohexane-like face.
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