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Time-dependent fifth-order bands in nominally third-order 2D IR vibrational echo spectra

Megan C Thielges1, Michael D Fayer

  • 1Department of Chemistry, Stanford University, Stanford, California 94305, USA.

The Journal of Physical Chemistry. A
|June 9, 2011
PubMed
Summary

Fifth-order signals in 2D IR spectra of carbon monoxide (CO) in cytochrome P450(cam) were observed. These novel signals, arising from higher-order vibrational transitions, require careful interpretation to distinguish them from other spectral features.

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