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X Li1, H Breitkreutz, J Burfeindt

  • 1Forschungs-Neutronenquelle Heinz Maier-Leibnitz, FRM II, Technische Universität München, Garching, Germany. xiaosong.li@frm2.tum.de

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Nuclear Overhauser Enhancement (NOE)01:06

Nuclear Overhauser Enhancement (NOE)

Irradiation of a spin-active nucleus causes an increase or decrease in the signal intensity of neighboring nuclei that are not necessarily chemically bonded or involved in J-coupling. This phenomenon, called the nuclear Overhauser enhancement (NOE), results from through-space interactions between the nuclear spins. The NOE effect decreases with increasing internuclear distance and is generally not observed beyond 4 angstroms. In NOE, dipole-dipole interactions between neighboring spin-active...