Stereodifferentiation in the compartmentalized photooxidation of a protein-bound anthracene
Rafael Alonso1, M Consuelo Jiménez, Miguel A Miranda
1Departamento de Química/Instituto de Tecnología Química UPV-CSIC, Universidad Politécnica de Valencia, Camino de Vera s/n, E-46022 Valencia, Spain.
Organic Letters
|June 25, 2011
Abstract:
Encapsulation within transport proteins strongly reduces the photooxidation rate of (S)- and (R)-2-(9-anthracenyl)propanoic acid (1) and results in a significant stereodifferentiation. The most remarkable effects are observed within human serum albumin (HSA).
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