Related Experiment Video
Updated: May 31, 2026

05:57
Quantitative 31P NMR Analysis of Lignins and Tannins
Published on: August 2, 2021
Relationship between red wine grade and phenolics. 2. Tannin composition and size
Stella Kassara1, James A Kennedy
1The Australian Wine Research Institute, Glen Osmond, SA, Australia.
Journal of Agricultural and Food Chemistry
|June 28, 2011
Summary
Higher concentrations of skin-derived tannins in red wines (Vitis vinifera L. cv. Shiraz) correlate with increased projected bottle price. This suggests optimizing skin tannin levels can enhance wine value.
Area of Science:
- Enology and Viticulture
- Food Chemistry
- Agricultural Economics
Background:
- Commercial red wines, specifically Vitis vinifera L. cv. Shiraz from the 2009 vintage, were assessed for quality grading.
- Phenolic compounds, crucial for wine color and structure, were analyzed.
Purpose of the Study:
- To investigate the relationship between phenolic composition, particularly tannins, and the projected market value of red wines.
- To determine if specific tannin characteristics influence wine grade and price.
Main Methods:
- Winemaker assessment for allocation grade.
- Phenolic analysis including total anthocyanins, non-bleachable pigment (SO(2)), and wine color density.
- Tannin analysis focusing on concentration, composition, and average degree of polymerization.
Main Results:
- A positive correlation was observed between overall wine phenolic concentration and projected bottle price.
- Skin-derived tannins were specifically linked to wine grade.
- Higher concentrations or proportions of skin tannins were associated with increased projected wine price.
Conclusions:
- Wine phenolic content, especially tannins derived from grape skins, is a significant factor in determining wine value.
- Maximizing skin tannin concentration and/or proportion may lead to higher projected bottle prices for Shiraz red wines.
Related Concept Videos
Acidity and Basicity of Alcohols and Phenols
Like water, alcohols are weak acids and bases. This is attributed to the polarization of the O–H bond making the hydrogen partially positive. Moreover, the electron pairs on the oxygen atom of alcohol make it both basic and nucleophilic. Protonation of an alcohol converts hydroxide, a poor leaving group, into water—a good one. The two acid–base equilibria corresponding to ethanol are depicted below.
Oxidation of Phenols to Quinones
In the presence of oxidizing agents, phenols are oxidized to quinones. Quinones can be easily reduced back to phenols using mild reducing agents. The electron-donating hydroxyl group enhances the reactivity of the aromatic ring, enabling oxidation of the ring even in the absence of an α hydrogen.
o-hydroxy phenols are oxidized to o-quinones and p-hydroxy phenols to p-quinones. Such redox reactions involve the transfer of two electrons and two protons. The reversible redox property is crucial in...
o-hydroxy phenols are oxidized to o-quinones and p-hydroxy phenols to p-quinones. Such redox reactions involve the transfer of two electrons and two protons. The reversible redox property is crucial in...
Structure and Nomenclature of Alcohols and Phenols
Overview
Alcohols are one of the most important functional groups in organic chemistry. The name of alcohol comes from the hydrocarbon from which it is derived. Alcohols are organic molecules containing the functional hydroxyl or –OH group directly bonded to carbon. Phenols have an OH group directly attached to a benzene ring. While alcohols are colorless, phenol is a white crystalline compound with a characteristic "hospital smell" odor.
As with other organic compounds, alcohols and phenols...
Alcohols are one of the most important functional groups in organic chemistry. The name of alcohol comes from the hydrocarbon from which it is derived. Alcohols are organic molecules containing the functional hydroxyl or –OH group directly bonded to carbon. Phenols have an OH group directly attached to a benzene ring. While alcohols are colorless, phenol is a white crystalline compound with a characteristic "hospital smell" odor.
As with other organic compounds, alcohols and phenols...
Classification of Titrimetric Analysis Based on Reaction Types
Titrimetric analysis in solution chemistry involves measuring the volume of solutions and is often called volumetric analysis. The standard solution of known concentration in the burette is called the titrant, whereas the solution of unknown concentration in the flask is called the analyte, or titrand. Titrimetric analyses can be classified into four types based on the reactions between the titrant and analyte.
Titrations between an acid and a base lead to neutralization reactions that form...
Titrations between an acid and a base lead to neutralization reactions that form...
Redox Titration: Overview
Redox titration is a chemical analysis technique used to determine the concentration of an unknown substance by measuring the electron transfer in a redox (reduction-oxidation) reaction. The process involves gradually adding a titrant with a known concentration of an oxidizing or reducing agent, to the analyte, the solution with an unknown concentration, until reaching the endpoint, which indicates the completion of the reaction between the two substances. Ensuring the analyte is in a single...
Physical Properties of Alcohols and Phenols
Alcohols are organic compounds in which a hydroxy group is attached to a saturated carbon. Phenols are a class of alcohols containing a hydroxy group attached to an aromatic ring. The physical properties of the alcohols and phenols are influenced by hydrogen bonding due to the oxygen–hydrogen dipole in the hydroxy functional group and dispersion forces between alkyl or aryl regions of alcohol and phenol molecules.
Alcohols possess a higher boiling point than aliphatic hydrocarbons of similar...
Alcohols possess a higher boiling point than aliphatic hydrocarbons of similar...

