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Characterization of Nanocrystal Size Distribution using Raman Spectroscopy with a Multi-particle Phonon Confinement Model
Published on: August 22, 2015
Effect of noise-induced nucleation on grain size distribution studied via the phase-field crystal method
J Hubert1, M Cheng, H Emmerich
1Computational Materials Engineering (CME), Institute for Minerals Engineering, Center for Computational Engineering Science, Jülich-Aachen Research Alliance, RWTH Aachen University, DE-52056 Aachen, Germany.
Abstract:
We contribute to the more detailed understanding of the phase-field crystal model recently developed by Elder et al (2002 Phys. Rev. Lett. 88 245701), by focusing on its noise term and examining its impact on the nucleation rate in a homogeneously solidifying system as well as on successively developing grain size distributions. In this context we show that principally the grain size decreases with increasing noise amplitude, resulting in both a smaller average grain size and a decreased maximum grain size. Despite this general tendency, which we interpret based on Panfilis and Filiponi (2000 J. Appl. Phys. 88 562), we can identify two different regimes in which nucleation and successive initial growth are governed by quite different mechanisms.
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