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Updated: May 31, 2026

Raman and IR Spectroelectrochemical Methods as Tools to Analyze Conjugated Organic Compounds
Published on: October 12, 2018
Application of linear Raman spectroscopy for the determination of acetone decomposition
Simone Christine Eichmann1, Johannes Trost, Thomas Seeger
1Lehrstuhl für Technische Thermodynamik, Universität Siegen, Siegen, Germany. Simone.Eichmann@ltt.uni-erlangen.de
Abstract:
Acetone (CH3)2CO is a common tracer for laser-induced fluorescence (LIF) to investigate mixture formation processes and temperature fields in combustion applications. Since the fluorescence signal is a function of temperature and pressure, calibration measurements in high pressure and high temperature cells are necessary. However, there is a lack of reliable data of tracer stability at these harsh conditions for technical application. A new method based on the effect of spontaneous Raman scattering is proposed to analyze the thermal stability of the tracer directly in the LIF calibration cell. This is done by analyzing the gas composition regarding educts and products of the reaction. First measurements at IC engine relevant conditions up to 750 K and 30 bar are presented.
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