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Related Concept Videos

Electronic Structure of Atoms02:28

Electronic Structure of Atoms


An atom comprises protons and neutrons, which are contained inside the dense, central core called the nucleus, with electrons present around the nucleus. Taking into account the wave–particle duality of electrons and the uncertainty in position around the nucleus, quantum mechanics provides a more accurate model for the atomic structure. It describes atomic orbitals as the regions around the nucleus where electrons of discrete energy exist, characterized by four quantum numbers:  n, l, ml, and...
Electron Configuration of Multielectron Atoms03:26

Electron Configuration of Multielectron Atoms

The alkali metal sodium (atomic number 11) has one more electron than the neon atom. This electron must go into the lowest-energy subshell available, the 3s orbital, giving a 1s22s22p63s1 configuration. The electrons occupying the outermost shell orbital(s) (highest value of n) are called valence electrons, and those occupying the inner shell orbitals are called core electrons. Since the core electron shells correspond to noble gas electron configurations, we can abbreviate electron...
Metallic Solids02:37

Metallic Solids

Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
Electron Configurations02:46

Electron Configurations

Electron configurations and orbital diagrams can be determined by applying the Aufbau principle (each added electron occupies the subshell of lowest energy available), Pauli exclusion principle (no two electrons can have the same set of four quantum numbers), and Hund’s rule of maximum multiplicity (whenever possible, electrons retain unpaired spins in degenerate orbitals).
The relative energies of the subshells determine the order in which atomic orbitals are filled (1s, 2s, 2p, 3s, 3p, 4s,...
Electron Behavior01:09

Electron Behavior

Electrons are negatively charged subatomic particles attracted to and orbit around the positively-charged nucleus of an atom. They reside in spaces associated with energy levels called shells and are further organized into subshells and orbitals within each shell.
Electrons Orbit the Nucleus
Electrons are found in specific locations outside of the nucleus. The shell in which an electron resides indicates the general energy level of the electron: those closer to the nucleus have less energy,...
Electron Behavior00:54

Electron Behavior

Overview
Electrons are negatively charged subatomic particles that are attracted to an orbit around the positively-charged nucleus of an atom. They reside in locations that are associated with energy levels called shells and are further organized into sub-shells and orbitals within each shell.
Electrons Orbit the Nucleus
Electrons are found in specific locations outside of the nucleus. The shell in which an electron resides indicates the general energy level of the electron: those closer to the...

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Related Experiment Video

Updated: May 31, 2026

Iron Nanowire Fabrication by Nano-Porous Anodized Aluminum and its Characterization
07:14

Iron Nanowire Fabrication by Nano-Porous Anodized Aluminum and its Characterization

Published on: October 6, 2019

Electronic and atomic shell structure in aluminium nanowires.

A I Mares1, D F Urban, J Bürki

  • 1Kamerlingh Onnes Laboratorium, Universiteit Leiden, PO Box 9504, 2300 RA Leiden, The Netherlands.

Nanotechnology
|July 7, 2011
PubMed
Summary

Experiments reveal exceptionally stable aluminium nanowire structures. Two series of stable structures are governed by electronic shell effects at low conductance and atomic packing at larger contacts.

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Area of Science:

  • Materials Science
  • Condensed Matter Physics
  • Nanotechnology

Background:

  • Understanding the stability of metallic nanowires is crucial for nanoscale electronics.
  • Previous studies on alkali and noble metals have highlighted electronic shell effects and atomic packing in nanowire formation.

Purpose of the Study:

  • To investigate the structural stability of aluminium nanowires.
  • To identify the governing principles behind the formation of stable aluminium nanowire structures.
  • To compare the behavior of aluminium nanowires with other metallic systems.

Main Methods:

  • Experimental investigation of aluminium nanowires in ultra-high vacuum at room temperature.
  • Analysis of conductance histograms to identify stable structures.
  • Theoretical stability analysis for comparison with experimental results.

Main Results:

  • Observation of a periodic spectrum of exceptionally stable aluminium nanowire structures.
  • Identification of two distinct series of stable structures: one governed by electronic shell effects (low conductance) and another by atomic packing (larger contacts).
  • Discovery of a unique series of extremely stable, 'superdeformed' non-axisymmetric nanowires in aluminium, isolated in conductance histograms.

Conclusions:

  • Aluminium nanowire stability is influenced by both electronic shell effects and atomic packing, with a smooth crossover between regimes.
  • Aluminium exhibits unique stable structures ('superdeformed' nanowires) not observed in alkali or noble metals.
  • These findings provide insights into the fundamental properties of metallic nanowires and their potential applications.