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One-step synthesis of highly water-soluble LaF(3):Ln(3+) nanocrystals in methanol without using any ligands
Jianshe Wang1, Shuhui Bo, Limei Song
1Laboratory of Organic Optoelectronic Functional Materials and Molecular Engineering, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080, People's Republic of China. Graduate University of Chinese Academy of Sciences, Beijing 100049, People's Republic of China.
Abstract:
Water-soluble infrared-to-visible fluorescent LaF(3) nanocrystals doped with different lanthanide ions (Er(3+)/Yb(3+), Eu(3+), Nd(3+), Tb(3+)) have been synthesized in methanol without using any ligands. These nanocrystals are easily dispersed in water, producing a transparent colloidal solution. The colloids of the Er(3+)/Yb(3+), Eu(3+), Nd(3+), Tb(3+) doped nanocrystals exhibit strong luminescence in the visible and near-infrared spectral regions.

