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Updated: May 31, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Electronic communication between two amine redox centers bridged by a bis(terpyridine)ruthenium(II) complex
Chang-Jiang Yao1, Jiannian Yao, Yu-Wu Zhong
1Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, People's Republic of China.
Abstract:
Two bis(terpyridine)ruthenium(II) complexes 2 and 3 appended with one or two di-p-anisylamino groups, respectively, were synthesized and fully characterized. Their electronic properties were studied by electrochemical and spectroscopic analyses. Electronic communication between individual amine sites of 3 was estimated by intervalence charge-transfer band analyses.
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