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Related Concept Videos

Colloids and Suspensions01:17

Colloids and Suspensions

Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
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Confocal Imaging of Confined Quiescent and Flowing Colloid-polymer Mixtures
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Published on: May 20, 2014

Anisotropic diffusion in confined colloidal dispersions: the evanescent diffusivity.

James W Swan1, John F Brady

  • 1Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA. jswan@caltech.edu

The Journal of Chemical Physics
|July 13, 2011
PubMed
Summary

Colloidal particle diffusion near a solid boundary is described using evanescent wave dynamic light scattering. Near the wall, particle movement is significantly impacted by lubrication interactions, especially at smaller penetration depths.

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Area of Science:

  • Colloid and Surface Science
  • Soft Matter Physics
  • Hydrodynamics

Background:

  • Understanding colloidal particle dynamics near solid boundaries is crucial for various applications.
  • Traditional dynamic light scattering (DLS) methods have limitations in probing near-boundary phenomena.
  • Evanescent wave dynamic light scattering (EW-DLS) offers a unique approach to study confined colloidal systems.

Purpose of the Study:

  • To develop a theoretical framework for inhomogeneous and anisotropic diffusion of colloidal particles near a solid boundary.
  • To investigate the influence of volume fraction and evanescent penetration depth on colloidal diffusivities.
  • To elucidate the role of hydrodynamic interactions and lubrication forces in near-wall colloidal dynamics.

Main Methods:

  • Employed an analogy to traditional dynamic light scattering for analyzing EW-DLS data.
  • Derived new expressions for short-time self- and collective diffusivities.
  • Utilized accelerated Stokesian dynamics simulations to compute diffusivities across various parameters.

Main Results:

  • At high volume fractions and larger penetration depths, parallel diffusion is minimally affected by the boundary.
  • Near and normal to the wall, diffusivity strongly depends on penetration depth due to lubrication interactions.
  • The study provides a comprehensive determination of hydrodynamic effects on colloidal diffusion adjacent to a rigid boundary.

Conclusions:

  • The developed model accurately describes near-wall colloidal diffusion, accounting for boundary effects.
  • Lubrication forces are identified as the dominant factor influencing diffusivity normal to the wall.
  • Results offer significant insights into the behavior of colloidal suspensions in confined geometries.