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Updated: May 31, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
(N-Butyl-N-phenyl-dithio-carbamato-κS)triphenyl-tin(IV)
Abstract:
The title compound, [Sn(C(6)H(5))(3)(C(11)H(14)NS(2))], features a tetra-hedrally coordinated Sn atom, as the dithio-carbamate ligand coordinates in a monodentate fashion. Due to the proximity of the non-coordinating thione S atom, distortions from ideal tetra-hedral geometry about the metal atom are evident with the widest C-Sn-S angle being 117.26 (5)°. In the crystal, mol-ecules are linked by C-H⋯S inter-actions, which generate helical supra-molecular chains along the b axis.
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