2-[4-(Methyl-sulfan-yl)phen-yl]naphtho[1,8-de][1,3,2]diaza-borinane
Cathryn A Slabber1, Matthew P Akerman, Ross S Robinson
1Warren Research Laboratory, School of Chemistry, University of KwaZulu Natal, Private Bag X01, Scottsville, Pietermaritzburg 3209, South Africa.
Abstract:
The title compound, C(17)H(15)BN(2)S, is one member in a series of diaza-borinanes featuring substitution at the 1-, 2- and 3-positions in the nitro-gen-boron heterocycle. The dihedral angle between the mean planes of the naphthalene and phenyl ring systems is 19.86 (6)°. In the crystal structure, two C-H⋯π inter-actions link the mol-ecules into sheets which lie parallel to the bc plane. There is a π-π inter-action between each pair of centrosymmetrically related sheets [centroid-centroid distance = 3.5922 (8) Å].
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