Stress enhancement in the delayed yielding of colloidal gels
Joris Sprakel1, Stefan B Lindström, Thomas E Kodger
1School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138, USA. joris.sprakel@gmail.com
Abstract:
Networks of aggregated colloidal particles are solidlike and can sustain an applied shear stress while exhibiting little or no creep; however, ultimately they will catastrophically fail. We show that the time delay for this yielding decreases in two distinct exponential regimes with applied stress. This behavior is universal and found for a variety of colloidal gel systems. We present a bond-rupture model that quantitatively describes this behavior and highlights the role of mesoscopic structures. Our result gives new insight into the nature of yielding in these soft solid materials.
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