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Synthesis and properties of a blue bipolar indenofluorene emitter based on a D-π-A design

Damien Thirion1, Joëlle Rault-Berthelot, Laurence Vignau

  • 1Université de Rennes 1 - UMR CNRS 6226 Sciences Chimiques de Rennes-MaCSE group, Bat 10C, Campus de Beaulieu - 35042 Rennes cedex, France.

Organic Letters
|July 28, 2011
PubMed

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Bromination and chlorination of aromatic rings by electrophilic aromatic substitution reactions are easily achieved, but fluorination and iodination are difficult to achieve. Fluorine is so reactive that its reaction with benzene is difficult to control, resulting in poor yields of monofluoroaromatic products. To address this, Selectfluor reagent is used as a fluorine source in which a fluorine atom is bonded to a positively charged nitrogen.
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UV–Vis Spectroscopy: Woodward–Fieser Rules

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