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Published on: October 5, 2019
A dyad as photocatalyst for light-driven sulfide oxygenation with water as the unique oxygen atom source
Olivier Hamelin1, Pascal Guillo, Frédérique Loiseau
1Laboratoire de Chimie et Biologie des Métaux-UMR 5249, Université Grenoble I-CNRS-CEA, CEA Grenoble-iRTSV, 17 avenue des Martyrs, 38054 Grenoble cedex 9, France. ohamelin@cea.fr
Abstract:
With the objective to convert light energy into chemical oxidation energy, a ruthenium-based dyad constituted of the assembly of a photosensitizer and a catalytic fragment was synthesized. Upon irradiation with blue LEDs, and in the presence of an electron acceptor, the complex is able to catalyze selective sulfide oxygenation involving an oxygen atom transfer from water to the substrate. Electrochemical and photophysical studies highlighted a proton-coupled electron transfer (PCET) to access to a high valent oxidant Ru(IV) oxo species.
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