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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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N-acetylmethionine and biotin as photocleavable protective groups for ruthenium polypyridyl complexes

Roosmarijn E Goldbach1, Isabel Rodriguez-Garcia, Joop H van Lenthe

  • 1Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|July 29, 2011
PubMed
Abstract

No abstract available in PubMed .

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Acetals are formed by reacting two equivalents of alcohol with carbonyl compounds like aldehydes or ketones. Acetals are unaffected by bases, nucleophiles, oxidizing agents, and reducing agents. They serve as protecting groups for aldehydes and ketones. Acetals can be easily formed and also easily removed via mild acid hydrolysis.
In the presence of multiple functional groups, when selective reduction of one group over the other is desired, groups like aldehydes and ketones that form acetals...