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Effects of the dielectric discontinuity on the counterion distribution in a colloidal suspension
Alexandre P dos Santos1, Amin Bakhshandeh, Yan Levin
1Instituto de Física, Universidade Federal do Rio Grande do Sul, Caixa Postal 15051, CEP 91501-970, Porto Alegre, RS, Brazil.
Abstract:
We introduce a new method for simulating colloidal suspensions with spherical colloidal particles of dielectric constant different from the surrounding medium. The method uses an approximate calculation of the Green function to obtain the ion-ion interaction potential in the presence of a dielectric discontinuity at the surface of the colloidal particle. The method is very accurate and is orders of magnitude faster than the traditional approaches based on series expansions of the interaction potential.
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